Material Safety Data Sheet

CALCIUM CHLORIDE

Product Identification

Synonyms: calcium dichloride; calcium chloride anhydrous, Caltac®; Dowflake
CAS No: 10043-52-4
Molecular Weight: 110.08
Chemical Formula: CaCl2
Product Codes: 0771.3266.3630.4225.4748.4777.4822.4870.4875.4880

Composition/Information on Ingredients

Ingredient: Calcium Chloride
CAS No.: 10043-52-4
Percent: 93 - 100%
Hazardous: Yes

Hazards Identification

Emergency Overview
WARNING! CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. HARMFUL IF SWALLOWED OR INHALED.

Potential Health Effects
Inhalation:
Granular material does not pose a significant inhalation hazard, but inhalation of dust may cause irritation to the respiratory tract, with symptoms of coughing and shortness of breath.

Ingestion:
Low toxicity material but ingestion may cause serious irritation of the mucous membrane due to heat of hydrolysis. Large amounts can cause gastrointestinal upset, vomiting, abdominal pain.

Skin Contact:
Solid may cause mild irritation on dry skin; strong solutions or solid in contact with moist skin may cause severe irritation, even burns.

Eye Contact:
Hazard may be either mechanical abrasion or, more serious, burns from heat of hydrolysis and chloride irritation.

Chronic Exposure:
No information found.

Aggravation of Pre-existing Conditions:
No information found.

First Aid Measures

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.

Skin Contact:
Wipe of excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Note to Physician:
Oral ingestion may cause serum acidosis.

Fire Fighting Measures

Fire:
Not considered to be a fire hazard.

Explosion:
Not considered to be an explosion hazard.

Fire Extinguishing Media:
Use any means suitable for extinguishing surrounding fire.

Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, calcium chloride may produce toxic or irritating fumes.

Accidental Release Measures
Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. Small amounts of residue may be flushed to sewer with plenty of water.

Handling and Storage
Keep in a tightly closed container, stored in a cool, dry ventilated area. Protect against physical damage. Moist calcium chloride and concentrated solutions can corrode steel. When exposed to the atmosphere, calcium chloride will absorb water and form a solution. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

Exposure Controls/Personal Protection
Airborne Exposure Limits:
None established.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation, A Manual of Recommended Practice," most recent edition, for details.

Personal Respirator (NIOSH Approved)
For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g.. lubricants, cutting fluids, glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protections:
Wear protective gloves and clean body-covering clothing.

Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

Other Control Measures:
Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards.

Physical and Chemical Properties

Appearance: White or gray-white granules.

Boiling Point: >1600ªC (>2912ªF)

Odor: Odorless

Melting Point: 772ªC (1422ªF)

Solubility: Freely soluble in water, exothermic

Vapor Density (Air=1) No information found.

Density: 2.15

Vapor Pressure (mm Hg): No information found.

pH: 8 - 9 Aqueous solution

Evaporation Rate (BuAc=1): No information found.

% Volatiles by volume @21ªC (70ªF): 0

Stability and Reactivity

Stability:
Stable under ordinary conditions of use and storage. Substance will pick up moisture from the air and go into solution if exposed in open containers.

Hazardous Decomposition Products:
Emits toxic chlorine fumes when heated to decomposition. May form hydrogen chloride in presence of sulfuric or phosphoric acids or with water at elevated temperatures.

Hazardous Polymerization:
Will not occur.

Incompatibilities:
Methyl vinyl ether, water, zinc, bromine trifluoride, mixtures of lime and boric acid, barium chloride, and 2-furan percarboxylic acid. Metals will slowly corrode in aqueous calcium chloride solutions. Aluminum (and alloys) and yellow brass will be attacked by calcium chloride.

Conditions to Avoid:
Incompatibles.

Toxicological Information
Oral rat LD50; 1000 mg/kg. Investigated as a turmorigen and mutagen.

Cancer Lists
---NTP Carcinogen---
Ingredient: Calcium Chloride (10043-52-4)
Known: No
Anticipated: No
IARC Category: None

Ecological Information

Environmental Fate:
Based on available information for Calcium Chloride anhydrous, this material will not biodegrade or bioaccumulate.

Environmental Toxicity:
The LC50/96-hour values for fish are over 100 mg/l.

Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations.

Dispose of container and unused contents in accordance with federal, state and local requirements.

Transport Information
Not regulated.

Regulatory Information
Chemical Inventory Status

Chemical Weapons Convention: No
TSCA 12(b): No
CDTA: No

SARA 311/312: Acute: Yes Chronic: No Fire: No Pressure: No Reactivity: No (Pure/Solid)

Australian Hazchem Code: No information found.
Australian Poison Schedule: No information found.
WHMIS: This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

Other Information

NFPA Ratings:
Health: 1 Flammability: 0 Reactivity: 1

Label Hazard Warning:
WARNING! CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. HARMFUL IF SWALLOWED OR INHALED.

Label Precautions:
Avoid contact with eyes, skin and clothing.
Wash thoroughly after handling.
Avoid breathing dust.
Keep container closed.
Use only with adequate ventilation.

Label First Aid:
If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. In case of contact, wipe off excess material from skin then immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In all cases, get medical attention.

Product Use:
Laboratory Reagent.

Revision Information:
MSDS Section(s) changed since last revision of document include: 8.

Disclaimer:
Mallinckrodt provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. MALLINCKRODT MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY. FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.
Prepared By: Environmental Health & Safety
Phone Number: (314) 654-1600 (U.S.A.)

SARA Section 302 EHS RQ: Reportable Quantity of Extremely Hazardous Substance,listed at 40 CFR 355.

SARA Section 302 EHS TPQ: Threshold Planning Quantity of Extremely HazardousSubstance. An asterisk (*) following a Threshold Planning Quantity signifies thatif the material is a solid and has a particle size equal to or larger than 100 micrometers,the Threshold Planning Quantity = 10,000 LBS.

SARA Section 313 Chemicals: Toxic Substances subject to annual releasereporting requirements listed at 40 CFR 376.65

CERCLA Sec. 103: Comprehensive Environmental Response, Compensation andLiability Act (Superfund). Releases to air, land or water of these hazardous substanceswhich exceed the Reportable Quantity (RQ) must be reported to the National ResponseCenter (800-424-8802); listed at 40 CFR 302.4

RCRA: Resource Conservation and Recovery Act. Commercial chemical productwastes designated as acute hazards and toxic under 40 CFR 261.33